Synthesis and characterization of metalorganic polymers of intrinsic microporosity based on iron(II) clathrochelate

Bassam Alameddine; Suchetha Shetty; Noorullah Baig; Saleh Al-Mousawi; Fakhreia Al-Sagheer

doi:10.1016/j.polymer.2017.06.048

Synthesis and characterization of metalorganic polymers of intrinsic microporosity based on iron(II) clathrochelate

Bassam Alameddine, Suchetha Shetty, Noorullah Baig, Saleh Al-Mousawi, Fakhreia Al-Sagheer

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Four Iron(II) clathrochelate derived polymers (P1-4) were synthesized under mild reaction conditions using iron(II) chloride with benzene-1,4-diboronic acid in presence of various vicinal dioxime moieties. The polymers were characterized by different instrumental analyses techniques and their structures were further confirmed by comparison of their respective synthesized prototypical monomers (M). Evaluation of P1-4 intrinsic microporosity was carried out by nitrogen adsorption measurements where polymer P4 reveals a Brunauer-Emmett-Teller (BET) surface area of 412 m²/g and average pore volume of 0.36 cm³/g.

Original language	English
Pages (from-to)	200-207
Number of pages	8
Journal	Polymer
Volume	122
DOIs	https://doi.org/10.1016/j.polymer.2017.06.048
State	Published - 28 Jul 2017

Keywords

Adsorption isotherms
Iron(II) clathrochelate
Polycondensation
Polymers of intrinsic microporosity
Surface area

Funding Agency

Kuwait Foundation for the Advancement of Sciences

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10.1016/j.polymer.2017.06.048

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title = "Synthesis and characterization of metalorganic polymers of intrinsic microporosity based on iron(II) clathrochelate",

abstract = "Four Iron(II) clathrochelate derived polymers (P1-4) were synthesized under mild reaction conditions using iron(II) chloride with benzene-1,4-diboronic acid in presence of various vicinal dioxime moieties. The polymers were characterized by different instrumental analyses techniques and their structures were further confirmed by comparison of their respective synthesized prototypical monomers (M). Evaluation of P1-4 intrinsic microporosity was carried out by nitrogen adsorption measurements where polymer P4 reveals a Brunauer-Emmett-Teller (BET) surface area of 412 m2/g and average pore volume of 0.36 cm3/g.",

keywords = "Adsorption isotherms, Iron(II) clathrochelate, Polycondensation, Polymers of intrinsic microporosity, Surface area",

author = "Bassam Alameddine and Suchetha Shetty and Noorullah Baig and Saleh Al-Mousawi and Fakhreia Al-Sagheer",

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T1 - Synthesis and characterization of metalorganic polymers of intrinsic microporosity based on iron(II) clathrochelate

AU - Alameddine, Bassam

AU - Shetty, Suchetha

AU - Baig, Noorullah

AU - Al-Mousawi, Saleh

AU - Al-Sagheer, Fakhreia

PY - 2017/7/28

Y1 - 2017/7/28

N2 - Four Iron(II) clathrochelate derived polymers (P1-4) were synthesized under mild reaction conditions using iron(II) chloride with benzene-1,4-diboronic acid in presence of various vicinal dioxime moieties. The polymers were characterized by different instrumental analyses techniques and their structures were further confirmed by comparison of their respective synthesized prototypical monomers (M). Evaluation of P1-4 intrinsic microporosity was carried out by nitrogen adsorption measurements where polymer P4 reveals a Brunauer-Emmett-Teller (BET) surface area of 412 m2/g and average pore volume of 0.36 cm3/g.

AB - Four Iron(II) clathrochelate derived polymers (P1-4) were synthesized under mild reaction conditions using iron(II) chloride with benzene-1,4-diboronic acid in presence of various vicinal dioxime moieties. The polymers were characterized by different instrumental analyses techniques and their structures were further confirmed by comparison of their respective synthesized prototypical monomers (M). Evaluation of P1-4 intrinsic microporosity was carried out by nitrogen adsorption measurements where polymer P4 reveals a Brunauer-Emmett-Teller (BET) surface area of 412 m2/g and average pore volume of 0.36 cm3/g.

KW - Adsorption isotherms

KW - Iron(II) clathrochelate

KW - Polycondensation

KW - Polymers of intrinsic microporosity

KW - Surface area

UR - https://www.scopus.com/pages/publications/85021416036

U2 - 10.1016/j.polymer.2017.06.048

DO - 10.1016/j.polymer.2017.06.048

M3 - Article

AN - SCOPUS:85021416036

SN - 0032-3861

VL - 122

SP - 200

EP - 207

JO - Polymer

JF - Polymer

ER -

Synthesis and characterization of metalorganic polymers of intrinsic microporosity based on iron(II) clathrochelate

Abstract

Keywords

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