Simplified cleaning for 22.5% nPERT solar cells with rear epitaxial emitters

I. Kuzma-Filipek, M. Recaman-Payo, M. Aleman, J. John, M. Haslinger, E. Cornagliotti, F. Duerinckx, A. Hajjiah, M. Soha, R. Russel, A. Sharma, A. Uruena, J. Szlufcik, I. Gordon

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

We have studied the effect of different cleanings at device level for nPERT (passivated Emitter, Rear Totally diffused) cells with a rear epitaxial emitter. Cleanings based on sulfuric acid and peroxide mixtures (SPM), which are effective but also expensive, were used as reference. We found that simplified cleanings such as those based on sulfuric acid and ozone mixtures (SOM), and those based on water and ozone (IPV), are giving similar results at device level as the expensive SPM cleaning, leading to similar J0e, J0, FSF, and lifetime values. The implied VOC values of corresponding test devices fabricated using the simplified cleanings are at the same high level as the test devices using more expensive SPM cleanings. Actual nPERT devices with moderately doped epitaxially-grown emitters with a constant doping profile (box profile) showed average efficiencies above 22.0% for both SOM and IPV cleanings. Very high VOC values of up to 695 mV and implied VOC values of up to 730 mV were shown for cells with a flat rear surface. Finally, the best nPERT cells with rear epitaxial emitter and SOM cleaning showed efficiencies up to 22.5%, as externally confirmed by ISE CalLab.

Original languageEnglish
Pages (from-to)19-23
Number of pages5
JournalSolar Energy Materials and Solar Cells
Volume158
DOIs
StatePublished - 1 Dec 2016

Keywords

  • Epitaxy
  • Npert
  • Ozone cleans

Funding Agency

  • Kuwait Foundation for the Advancement of Sciences

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