Mechanical, structural and thermal properties of Ag-Cu and ZnO reinforced polylactide nanocomposite films

Jasim Ahmed; Yasir Ali Arfat; Edgar Castro-Aguirre; Rafael Auras

doi:10.1016/j.ijbiomac.2016.02.034

Mechanical, structural and thermal properties of Ag-Cu and ZnO reinforced polylactide nanocomposite films

Jasim Ahmed, Yasir Ali Arfat, Edgar Castro-Aguirre, Rafael Auras

Kuwait Institute for Scientific Research

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

Plasticized polylactic acid (PLA) based nanocomposite films were prepared by incorporating polyethylene glycol (PEG) and two selected nanoparticles (NPs) [silver-copper (Ag-Cu) alloy (<100 nm) and zinc oxide (ZnO) (<50 and <100 nm)] through solvent casting method. Incorporation of Ag-Cu alloy into the PLA/PEG matrix increased the glass transition temperature (T_g) significantly. The crystallinity of the nanocomposites (NCs) was significantly influenced by NP incorporation as evidenced from differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analysis. The PLA nanocomposite reinforced with NPs exhibited much higher tensile strength than that of PLA/PEG blend. Melt rheology of NCs exhibited a shear-thinning behavior. The mechanical property drastically reduced with a loading of NPs, which is associated with degradation of PLA. SEM micrographs exhibited that both Ag-Cu alloy and ZnO NPs were dispersed well in the PLA film matrix.

Original language	English
Pages (from-to)	885-892
Number of pages	8
Journal	International Journal of Biological Macromolecules
Volume	86
DOIs	https://doi.org/10.1016/j.ijbiomac.2016.02.034
State	Published - 1 May 2016

Keywords

Glass transition temperature
Melt rheology
Tensile strength
X-ray diffraction

Funding Agency

Kuwait Foundation for the Advancement of Sciences

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10.1016/j.ijbiomac.2016.02.034

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@article{42289228738a45eca417b2fa0c28b156,

title = "Mechanical, structural and thermal properties of Ag-Cu and ZnO reinforced polylactide nanocomposite films",

abstract = "Plasticized polylactic acid (PLA) based nanocomposite films were prepared by incorporating polyethylene glycol (PEG) and two selected nanoparticles (NPs) [silver-copper (Ag-Cu) alloy (<100 nm) and zinc oxide (ZnO) (<50 and <100 nm)] through solvent casting method. Incorporation of Ag-Cu alloy into the PLA/PEG matrix increased the glass transition temperature (Tg) significantly. The crystallinity of the nanocomposites (NCs) was significantly influenced by NP incorporation as evidenced from differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analysis. The PLA nanocomposite reinforced with NPs exhibited much higher tensile strength than that of PLA/PEG blend. Melt rheology of NCs exhibited a shear-thinning behavior. The mechanical property drastically reduced with a loading of NPs, which is associated with degradation of PLA. SEM micrographs exhibited that both Ag-Cu alloy and ZnO NPs were dispersed well in the PLA film matrix.",

keywords = "Glass transition temperature, Melt rheology, Tensile strength, X-ray diffraction",

author = "Jasim Ahmed and Arfat, \{Yasir Ali\} and Edgar Castro-Aguirre and Rafael Auras",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = may,

day = "1",

doi = "10.1016/j.ijbiomac.2016.02.034",

language = "English",

volume = "86",

pages = "885--892",

journal = "International Journal of Biological Macromolecules",

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T1 - Mechanical, structural and thermal properties of Ag-Cu and ZnO reinforced polylactide nanocomposite films

AU - Ahmed, Jasim

AU - Arfat, Yasir Ali

AU - Castro-Aguirre, Edgar

AU - Auras, Rafael

PY - 2016/5/1

Y1 - 2016/5/1

N2 - Plasticized polylactic acid (PLA) based nanocomposite films were prepared by incorporating polyethylene glycol (PEG) and two selected nanoparticles (NPs) [silver-copper (Ag-Cu) alloy (<100 nm) and zinc oxide (ZnO) (<50 and <100 nm)] through solvent casting method. Incorporation of Ag-Cu alloy into the PLA/PEG matrix increased the glass transition temperature (Tg) significantly. The crystallinity of the nanocomposites (NCs) was significantly influenced by NP incorporation as evidenced from differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analysis. The PLA nanocomposite reinforced with NPs exhibited much higher tensile strength than that of PLA/PEG blend. Melt rheology of NCs exhibited a shear-thinning behavior. The mechanical property drastically reduced with a loading of NPs, which is associated with degradation of PLA. SEM micrographs exhibited that both Ag-Cu alloy and ZnO NPs were dispersed well in the PLA film matrix.

AB - Plasticized polylactic acid (PLA) based nanocomposite films were prepared by incorporating polyethylene glycol (PEG) and two selected nanoparticles (NPs) [silver-copper (Ag-Cu) alloy (<100 nm) and zinc oxide (ZnO) (<50 and <100 nm)] through solvent casting method. Incorporation of Ag-Cu alloy into the PLA/PEG matrix increased the glass transition temperature (Tg) significantly. The crystallinity of the nanocomposites (NCs) was significantly influenced by NP incorporation as evidenced from differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analysis. The PLA nanocomposite reinforced with NPs exhibited much higher tensile strength than that of PLA/PEG blend. Melt rheology of NCs exhibited a shear-thinning behavior. The mechanical property drastically reduced with a loading of NPs, which is associated with degradation of PLA. SEM micrographs exhibited that both Ag-Cu alloy and ZnO NPs were dispersed well in the PLA film matrix.

KW - Glass transition temperature

KW - Melt rheology

KW - Tensile strength

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84958259546

U2 - 10.1016/j.ijbiomac.2016.02.034

DO - 10.1016/j.ijbiomac.2016.02.034

M3 - Article

C2 - 26893045

AN - SCOPUS:84958259546

SN - 0141-8130

VL - 86

SP - 885

EP - 892

JO - International Journal of Biological Macromolecules

JF - International Journal of Biological Macromolecules

ER -

Mechanical, structural and thermal properties of Ag-Cu and ZnO reinforced polylactide nanocomposite films

Abstract

Keywords

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