Highly soluble metal-organic polymers based on iron(II) clathrochelates and their gelation induced by sonication

Bassam Alameddine; Suchetha Shetty; Rajamohanan Sobhana Anju; Fakhreia Al-Sagheer; Saleh Al-Mousawi

doi:10.1016/j.eurpolymj.2017.08.049

Highly soluble metal-organic polymers based on iron(II) clathrochelates and their gelation induced by sonication

Bassam Alameddine, Suchetha Shetty, Rajamohanan Sobhana Anju, Fakhreia Al-Sagheer, Saleh Al-Mousawi

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A series of clathrochelate polymers are reported by reacting iron(II) chloride with 9,9-dialkyl fluorene-2,7-diboronic acid and various vicinal dioxime units. The novel polymers were fully characterized by ¹H and ¹³C nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), X-ray photoelectron spectroscopy (XPS), and UV–Vis absorption spectroscopy. The linearly-linked 2D organometallic polymers form oragnogel from 10 wt% concentrations in organic solvents of low and medium polarity.

Original language	English
Pages (from-to)	566-574
Number of pages	9
Journal	European Polymer Journal
Volume	95
DOIs	https://doi.org/10.1016/j.eurpolymj.2017.08.049
State	Published - Oct 2017

Keywords

ESCA/XPS
Gels
GPC
Inorganic polymer
Polycondensation

Funding Agency

Kuwait Foundation for the Advancement of Sciences

Access to Document

10.1016/j.eurpolymj.2017.08.049

Cite this

@article{bb1dff88cdf04f8a81e90ca6883845b5,

title = "Highly soluble metal-organic polymers based on iron(II) clathrochelates and their gelation induced by sonication",

abstract = "A series of clathrochelate polymers are reported by reacting iron(II) chloride with 9,9-dialkyl fluorene-2,7-diboronic acid and various vicinal dioxime units. The novel polymers were fully characterized by 1H and 13C nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), X-ray photoelectron spectroscopy (XPS), and UV–Vis absorption spectroscopy. The linearly-linked 2D organometallic polymers form oragnogel from 10 wt% concentrations in organic solvents of low and medium polarity.",

keywords = "ESCA/XPS, Gels, GPC, Inorganic polymer, Polycondensation",

author = "Bassam Alameddine and Suchetha Shetty and Anju, {Rajamohanan Sobhana} and Fakhreia Al-Sagheer and Saleh Al-Mousawi",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2017",

month = oct,

doi = "10.1016/j.eurpolymj.2017.08.049",

language = "English",

volume = "95",

pages = "566--574",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Highly soluble metal-organic polymers based on iron(II) clathrochelates and their gelation induced by sonication

AU - Alameddine, Bassam

AU - Shetty, Suchetha

AU - Anju, Rajamohanan Sobhana

AU - Al-Sagheer, Fakhreia

AU - Al-Mousawi, Saleh

PY - 2017/10

Y1 - 2017/10

N2 - A series of clathrochelate polymers are reported by reacting iron(II) chloride with 9,9-dialkyl fluorene-2,7-diboronic acid and various vicinal dioxime units. The novel polymers were fully characterized by 1H and 13C nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), X-ray photoelectron spectroscopy (XPS), and UV–Vis absorption spectroscopy. The linearly-linked 2D organometallic polymers form oragnogel from 10 wt% concentrations in organic solvents of low and medium polarity.

AB - A series of clathrochelate polymers are reported by reacting iron(II) chloride with 9,9-dialkyl fluorene-2,7-diboronic acid and various vicinal dioxime units. The novel polymers were fully characterized by 1H and 13C nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), X-ray photoelectron spectroscopy (XPS), and UV–Vis absorption spectroscopy. The linearly-linked 2D organometallic polymers form oragnogel from 10 wt% concentrations in organic solvents of low and medium polarity.

KW - ESCA/XPS

KW - Gels

KW - GPC

KW - Inorganic polymer

KW - Polycondensation

UR - http://www.scopus.com/inward/record.url?scp=85028759900&partnerID=8YFLogxK

U2 - 10.1016/j.eurpolymj.2017.08.049

DO - 10.1016/j.eurpolymj.2017.08.049

M3 - Article

AN - SCOPUS:85028759900

SN - 0014-3057

VL - 95

SP - 566

EP - 574

JO - European Polymer Journal

JF - European Polymer Journal

ER -

Highly soluble metal-organic polymers based on iron(II) clathrochelates and their gelation induced by sonication

Abstract

Keywords

Funding Agency

Access to Document

Other files and links

Fingerprint

Cite this