Cost and energy needs of RO-ED-crystallizer systems for zero brine discharge seawater desalination

A zero brine discharge seawater desalination concept integrating reverse osmosis (RO), electrodialysis (ED) and crystallizer into a single system (REC) is presented. Analytical models were used to optimize parameters and minimize water production costs. Parameters varied were: the ratio of seawater to RO brine in the ED diluate channel, ED current density, ED diluate outlet salinity, electricity and salt prices, and RO recovery by adding high pressure RO (HPRO). Using only RO brine instead of only seawater in the ED diluate channel reduced water production costs by 87% from 27 to 3.5 $/m³ while increasing salt production costs 26% from 135 to 170 $/tonne-salt. The former was best for brine minimization, and the latter for salt production. Optimizing ED current density reduced REC costs by another 14% to 3.0 $/m³ while increasing specific energy consumption 26% to 12.7 kWh_e/m³, corresponding to a Second Law efficiency of 18%. Adding an HPRO stage was uneconomical as it increased specific costs 21%. A salt price of 104.5 $/tonne-salt will justify the cost of adding an ED-crystallizer. REC systems may be economically feasible in parts of the Middle-East. Producing other products such as Mg(OH)₂ or Br₂ may further improve economics.